A Funny Thing Happened on the Way to Thor's Hammer

Coulson stops at a petrol station on the way to New Mexico, disarms two armed robbers without raising his voice, and pays for his snacks.

It is a single scene and it exists to make one point about a character the films had been using as furniture: Phil Coulson is not the mild man he performs. He handles two people with guns in about eight seconds and then finishes his shopping.

The title is longer than the film.